Robert Boyle


Robert Boyle was an Anglo-Irish natural philosopher, chemist, physicist, alchemist and inventor. Boyle is largely regarded today as the first modern chemist, and therefore one of the founders of modern chemistry, and one of the pioneers of modern experimental scientific method.
He is best known for Boyle's law, which describes the inversely proportional relationship between the absolute pressure and volume of a gas, if the temperature is kept constant within a closed system.
Among his works, The Sceptical Chymist is seen as a cornerstone book in the field of chemistry. He was a devout and pious Anglican and is noted for his works in theology.

Biography

Early years

Boyle was born at Lismore Castle in County Waterford, in the far south of Ireland, the seventh son and fourteenth child of the 1st Earl of Cork and Catherine Fenton. Lord Cork, then known simply as Richard Boyle, had arrived in Dublin from England in 1588 during the Tudor plantations of Ireland and obtained an appointment as a deputy escheator. He had amassed enormous wealth and landholdings by the time Robert was born and had been made Earl of Cork in October 1620. Catherine, his wife, was the daughter of Sir Geoffrey Fenton, the former Secretary of State for Ireland, who was born in Dublin in 1539, and Alice Weston, the daughter of Robert Weston, who was born in Lismore in 1541.
As a child, Boyle was raised by a wet nurse, as were his elder brothers. Boyle received private tutoring in Latin, Greek, and French and when he was eight years old, following the death of his mother, he, and his brother Francis, were sent to Eton College in England. His father's friend, Sir Henry Wotton, was then the provost of the college.
During this time, his father hired a private tutor, Robert Carew, who had knowledge of Irish, to act as a private tutor to his sons in Eton. However, "only Mr. Robert sometimes desires it and is a little entered in it", but despite the "many reasons" given by Carew to draw their attention to it, "they practise the French and Latin but they affect not the Irish". After spending over three years at Eton, Robert travelled abroad with a French tutor. They visited Italy in 1641 and remained in Florence during the winter of that year studying the "paradoxes of the great star-gazer", the elderly Galileo Galilei.

Middle years

Robert returned to England from continental Europe in mid-1644 with a keen interest in scientific research. His father, Lord Cork, had died the previous year and had left him the manor of Stalbridge in Dorset as well as substantial estates in County Limerick in Ireland that he had acquired. Robert then made his residence at Stalbridge House, between 1644 and 1652, and settled in a laboratory where he conducted many experiments. From that time, Robert devoted his life to scientific research and soon took a prominent place in the band of enquirers, known as the "Invisible College", who devoted themselves to the cultivation of the "new philosophy". They met frequently in London, often at Gresham College, and some of the members also had meetings at Oxford.
Having made several visits to his Irish estates beginning in 1647, Robert moved to Ireland in 1652 but became frustrated at his inability to make progress in his chemical work. In one letter, he described Ireland as "a barbarous country where chemical spirits were so misunderstood and chemical instruments so unprocurable that it was hard to have any Hermetic thoughts in it."
All Souls, Oxford University, shows the arms of Boyle's family in the colonnade of the Great Quadrangle, opposite the arms of the Hill family of Shropshire, close by a sundial designed by Boyle's friend Christopher Wren.
In 1654, Boyle left Ireland for Oxford to pursue his work more successfully. An inscription can be found on the wall of University College, Oxford, the High Street at Oxford, marking the spot where Cross Hall stood until the early 19th century. It was here that Boyle rented rooms from the wealthy apothecary who owned the Hall.
Reading in 1657 of Otto von Guericke's vacuum pump, he set himself, with the assistance of Robert Hooke, to devise improvements in its construction. His "machina Boyleana" or "Pneumatical Engine" was finished in 1659.
Among the critics of the views put forward in this book was a Jesuit, Francis Line, and it was while answering his objections that Boyle made his first mention of the law that the volume of a gas varies inversely to the pressure of the gas, which among English-speaking people is usually called Boyle's law, after his name. The person who originally formulated the hypothesis was Henry Power in 1661. Boyle in 1662 included a reference to a paper written by Power, but mistakenly attributed it to Richard Towneley. In continental Europe, the hypothesis is sometimes attributed to Edme Mariotte, although he did not publish it until 1676 and was probably aware of Boyle's work at the time.
In 1663 the Invisible College became The Royal Society of London for Improving Natural Knowledge, and the charter of incorporation granted by Charles II of England named Boyle a member of the council. In 1680 he was elected president of the society but declined the honour from a scruple about oaths.
He made a "wish list" of 24 possible inventions which included "the prolongation of life", the "art of flying", "perpetual light", "making armour light and extremely hard", "a ship to sail with all winds, and a ship not to be sunk", "practicable and certain way of finding longitudes", "potent drugs to alter or exalt imagination, waking, memory and other functions and appease pain, procure innocent sleep, harmless dreams, etc.". All but a few of the 24 have come true.
In 1668 he left Oxford for London where he resided at the house of his elder sister Katherine Jones, Lady Ranelagh, in Pall Mall. He experimented in the laboratory she had in her home and attended her salon of intellectuals interested in the sciences. The siblings maintained "a lifelong intellectual partnership, where brother and sister shared medical remedies, promoted each other's scientific ideas, and edited each other's manuscripts." His contemporaries widely acknowledged Katherine's influence on his work, but later historiographers dropped discussion of her accomplishments and relationship to her brother from their histories.

Later years

In 1669 his health, never very strong, began to fail seriously and he gradually withdrew from his public engagements, ceasing his communications to the Royal Society, and advertising his desire to be excused from receiving guests, "unless upon occasions very extraordinary", on Tuesday and Friday forenoon, and Wednesday and Saturday afternoon. In the leisure thus gained he wished to "recruit his spirits, range his papers", and prepare some important chemical investigations which he proposed to leave "as a kind of Hermetic legacy to the studious disciples of that art", but of which he did not make known the nature. His health became still worse in 1691, and he died on 31 December that year, just a week after the death of his sister, Katherine, in whose home he had lived and with whom he had shared scientific pursuits for more than twenty years. Boyle died from paralysis. He was buried in the churchyard of St Martin-in-the-Fields, his funeral sermon being preached by his friend, Bishop Gilbert Burnet. In his will, Boyle endowed a series of lectures that came to be known as the Boyle Lectures.

Scientific contributions

Boyle's great merit as a scientific investigator is that he carried out the principles which Francis Bacon espoused in the Novum Organum. Yet he would not avow himself a follower of Bacon, or indeed of any other teacher.

Emphasis on experiments

On several occasions, he mentions that to keep his judgment as unprepossessed as might be with any of the modern theories of philosophy, until he was "provided of experiments" to help him judge of them. He refrained from any study of the atomical and the Cartesian systems, and even of the Novum Organum itself, though he admits to "transiently consulting" them about a few particulars. Nothing was more alien to his mental temperament than the spinning of hypotheses. "I,... love not to believe any thing upon Conjectures, when by a not over-difficult Experiment I can try whether it be True or no..."
He regarded the acquisition of knowledge as an end in itself, and in consequence, he gained a wider outlook on the aims of scientific inquiry than had been enjoyed by his predecessors for many centuries. This, however, did not mean that he paid no attention to the practical application of science, nor that he despised practical knowledge.

Physics and Chemistry

Vacuum pump

To Boyle, Guericke's vacuum pump had two important limitations. Firstly, its evacuation required "the continual labour of two strong men for divers hours", and secondly, "the Receiver, or Glass to be empty'd, consisting of one entire and uninterrupted Globe... of Glass... is so made, that things cannot be convey'd into it". Hooke constructed a pump that could be operated on a desktop, and conveniently opened to insert candles, mice, birds, bells, pendulums, and other research objects. With Hooke's pump, Boyle began a series of experiments on the properties of air. An account of Boyle's work with the pump was published in 1660 under the title New Experiments Physico-Mechanical, Touching the Spring of the Air, and its Effects.

Chemistry

Robert Boyle was an alchemist; and believing the transmutation of metals to be a possibility, he carried out experiments in the hope of achieving it; and he was instrumental in obtaining the repeal, by the Royal Mines Act 1688, of the statute of Henry IV against multiplying gold and silver, the Gold and Silver Act 1403. With all the important work he accomplished in physics, chemistry was his peculiar and favourite study. His first book on the subject was The Sceptical Chymist, published in 1661, in which he criticised the "experiments whereby vulgar Spagyrists are wont to endeavour to evince their Salt, Sulphur and Mercury to be the true Principles of Things". For him, chemistry was the science of the composition of substances, not merely an adjunct to the arts of the alchemist or the physician.